1905 – Pe. Gabriel Lux, SCJ
1919 – Pe. Francisco Schueller, SCJ
1920 – Pe. José Rogmann, SCJ
1926 – Pe. Lourenço Foxius, SCJ
1927 – Pe. Jaime de Barros Câmara
1936 – Pe. Bernardo Peters
1946 – Pe. Afonso Niehues
1959 – Pe. Valentim Loch
1971 – Pe. Vito Schlickmann
1984 – Pe. João Francisco Salm
1992 – Pe. Bertolino Schlickmann
1996 – Pe. Francisco Rohling
1999 – Pe. Luís Antônio Caon
2006 – Pe. Siro Manoel de Oliveira
2009 – Pe. Pedro Schlichting
2016 – Pe. Francisco de Assis Wloch